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20
years ago, odor and corrosion were considered nuisance
issues. Today, they have become serious problems
that adversely impact our quality of life.
So.....what changed?
Most
municipalities testing for sulfides observed a steady rise
from the early 1980’s to mid 90’s. These changes were
subtle, yet very significant to odor and corrosion.
Many municipalities did not measure sulfides, but
increases of 1500% were not uncommon where tested. (data
courtesy of the City of LA, CA)
A variety of
factors have contributed to increased sulfides:
-
longer
retention times caused by urban sprawl and centralized
treatment strategies,

-
low flow
plumbing fixtures, and ...
-
legislative
changes impacting sewage biochemistry.
To protect
public health the EPA enacted the 1983 Categorical
Pretreatment Act. This legislation severely reduced metals
limits for industrial dischargers.
Analysis
of influent metals clearly shows the change in chemistry
caused by
pretreatment.
In the
absence of metals bacterial activity increases. At
dissolved oxygen above 1 mg/l aerobes reduce organic
matter via oxidation.
Very
little sulfide is produced at this stage.
Without
metals to control bacterial growth, oxygen is more quickly
depleted. At <0.1 mg/l dissolved oxygen anaerobic
bacteria reduce sulfates to sulfide.
Although
reducing metals was necessary to protect public health, as
the graph (left) shows, pretreatment has contributed
significantly to increased odors and accelerated
corrosion.
The
primary reasons hydrogen sulfide levels have risen are
pretreatment and longer retention times.
Sewage has
changed. If your odor and corrosion control program hasn't
improved...expect more unhappy customers.
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